Rubies have a hardness of
9.0 on the Mohs scale of
mineral hardness.
Ruby is α-alumina (the
most stable form of Al2O3) in which a small fraction of
the aluminium3+ ions
are replaced by chromium3+ ions.
Each Cr3+ is
surrounded octahedrally by six O2- ions.
This crystallographic
arrangement strongly affects each Cr3+, resulting in light
absorption in the yellow-green region of the spectrum and thus in the red color
of the gem.
When yellow-green light
is absorbed by Cr3+, it is re-emitted as red luminescence this red emission adds
to the red color perceived by the subtraction of green and violet light from
white light, and adds luster to the gem's appearance. When the optical
arrangement is such that the emission is stimulated by 694-nano meter photons
reflecting back and forth between two mirrors, the emission grows strongly in
intensity. This effect was used by Theodore Maiman in 1960 to make the first successful laser, based on ruby.
All natural rubies have
imperfections in them, including color impurities and inclusions of rutile needles known as "silk".
Gemologists use these needle inclusions found in natural rubies to distinguish
them from synthetics, simulants, or substitutes. Usually the rough stone is
heated before cutting. Almost all rubies today are treated in some form, with
heat treatment being the most common practice. However, rubies that are
completely untreated but still of excellent quality command a large premium.
Some rubies show a
three-point or six-point asterism or
"star". These rubies are cut into cabochons to display the effect properly.
Asterisms are best visible with a single-light source, and move across the
stone as the light moves or the stone is rotated. Such effects occur when light
is reflected off the "silk" (the structurally oriented rutile needle inclusions) in a
certain way. This is one example where inclusions increase the value of a
gemstone. Furthermore, rubies can show color changes—though this occurs very
rarely—as well as chatoyancy or the
" cat's eye " effect.
Color
Generally,
gemstone-quality corundum in all shades of red, including pink, is called
rubies. However, in the United
States, minimum color saturation must be met to be called a ruby; otherwise the
stone will be called a pink sapphire.
This distinction between
rubies and pink sapphires is relatively new, having arisen sometime in the 20th
century. If a distinction is made, the line separating a ruby from a pink
sapphire is not clear and highly debated.
As a result of the
difficulty and subjectiveness of such distinctions, trade organizations such as
the International Colored Gemstone Association (ICA)
have adopted the broader definition for ruby which encompasses its lighter
shades, including pink.
Natural occurrence-
The Mogok Valley in Myanmar (Burma)
was for centuries the world's main source for rubies. That region has produced
some of the finest rubies, but in recent years very few good rubies have been
found there. The very best color in Myanmar rubies is sometimes described as
"pigeon's blood. The most recently found ruby deposit in Myanmar is in
Namya (Namyazeik) located in the northern state of Kachin.
Rubies have historically
been mined in Thailand, the
Pailin and Samlout
Districts of Cambodia, Burma,India, Afganistan and inPakistan. In Srilanka, lighter
shades of rubies (often "pink sapphires") are more commonly found. Ruby deposits were also found in Tanzania,Madagaskar, Vietnam, Nepal,Tajikistan, and Pakistan.
More recently,large ruby
deposits have been found under
the receding ice shelf of Greenland.
Spinal, another red gemstone, is sometimes
found along with rubies in the same gem gravel or marble. Red spinel may be
mistaken for ruby by those lacking experience with gems. However, the finest
red spinels can have a value approaching that of the average ruby. The color of rubies varies from
vermilion to red. The most desired color is "pigeon's blood", which
is pure red with a hint of blue. If the color is too pink, the stone is a pink
sapphire. The same is true if it is too violet – it is a violet sapphire. The
best rubies and star rubies are bright red. Most rubies come from Burma and
Thailand.
Treatments and enhancements
Improving the quality of
gemstones by treating them is common practice. Some treatments are used in
almost all cases and are therefore considered acceptable. During the late
1990s, a large supply of low-cost materials caused a sudden surge in supply of
heat-treated rubies, leading to a downward pressure on ruby prices.
Improvements used
include color alteration, improving transparency by dissolving rutile
inclusions, healing of fractures (cracks) or even completely filling them.
The most common
treatment is the application of heat. Most, if not all, rubies at the lower end
of the market are heat treated on the rough stones to improve color, remove purple tinge, blue patches and
silk. These heat treatments typically occur around temperatures of 1800 °C
(3300 °F). Some rubies undergo a
process of low tube heat, when the stone is heated over charcoal of a
temperature of about 1300 °C (2400 °F) for 20 to 30 minutes. The silk is only
partially broken as the color is improved.
Another treatment, which
has become more frequent in recent years, is lead glass filling. Filling the
fractures inside the ruby with lead glass (or
a similar material) dramatically improves the transparency of the stone, making
previously unsuitable rubies fit for applications in jewelry. The process is done in four steps:
Factors affecting value-
Diamonds
are graded using criteria that have become known as the four Cs, namely color,
cut, clarity and carat weight. Similarly natural rubies can be evaluated using
the four Cs together with their size and geographic origin.
Color: In the evaluation of colored
gemstones, color is the most important factor. Color divides into three
components; hue, saturation and tone. Hue refers to
"color" as we normally use the term. Transparent gemstones occur in
the following primary hues: red, orange, yellow, and green, blue, violet. These
are known as pure spectral
hues. In nature there are
rarely pure hues so when speaking of the hue of a gemstone we speak of primary
and secondary and sometimes tertiary hues. In ruby the primary hue must be red.
All other hues of the gem species corundum are called sapphire. Ruby may
exhibit a range of secondary hues. Orange, purple, violet and pink are possible.